KM2110

2-Hydroxyethyl methacrylate phosphate (HEMAP)

R-O-P(=O)(OH)₂ CAS 52628-03-2 EINECS 258-053-2
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Core profile KM2110

KM2110 is the highest-acid-value monofunctional phosphate monomer in the range (265–315 mgKOH/g). It delivers the strongest adhesion to metals, glass and ceramics and is also the standard HEMAP building block for clay-tolerant polycarboxylate superplasticizers.

Technical data

AppearanceClear transparent liquid
Color (Hazen)≤30
Acid value (mgKOH/g)265–315
Free acid (wt%)≤3.0
Viscosity (mPa·s, 25℃)700–1400
Density (g/ml, 25℃)1.240–1.350
Water content (wt%)≤0.1
Inhibitor MEHQ (ppm)300–500

Values are typical. The latest TDS and batch COA govern.

Key features

  • Highest acid value and polarity — best adhesion to metal and glass
  • Low color and very low odor
  • Effective at 0.5–3%, low cost in use
  • Copolymerizes into the network — no migration

Typical applications

  • Adhesion promoter for UV coatings, inks and adhesives
  • Vacuum metallizing and NCVM base coats
  • Nail gel base coats (bonds to nail hydroxyapatite)
  • Phosphorus source for halogen-free flame retardant resins
  • Clay-tolerant polycarboxylate superplasticizers

FAQ

How do I choose between KM2110 and KM2120?

Choose KM2110 when maximum adhesion to metal or glass matters. Choose KM2120 when you need color ≤10 Hazen, low shrinkage and higher crosslink density. The two can be blended.

Can KM2110 be used in amine-cured epoxy?

Not directly. Its high acid value neutralizes amine hardeners and shortens pot life, and its acrylate double bond has no reaction partner in an epoxy system. Use an epoxy silane instead, or apply KM2110 as a separate primer.

What dosage should I start with?

0.5–3% on total formulation, starting at 1% and running a ladder. Overdosing increases hydrophilicity and degrades water and salt-spray resistance.